(E)-N′-[3-(4-Chlorobenzoyloxy)benzylidene]pyridine-4-carbohydrazide acetic acid monosolvate monohydrate

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(E)-N′-[3-(4-Chloro­benzo­yloxy)benzyl­idene]pyridine-4-carbohydrazide acetic acid monosolvate monohydrate

In the Schiff base mol-ecule of the title compound, C(20)H(14)ClN(3)O(3)·CH(3)COOH·H(2)O, the central benzene ring makes dihedral angles of 36.26 (7) and 27.59 (8)°, respectively, with the terminal chloro-phenyl and pyridine rings. In the crystal, the three components are linked by O-H⋯O, N-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds into a double-tape structure along the a axis.

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N′-[(E)-4-Chloro­benzyl­idene]pyridine-4-carbohydrazide monohydrate

The asymmetric unit of the title compound, C(13)H(10)ClN(3)O·H(2)O, consists of two crystallographically independent Schiff base mol-ecules which exist in an E conformation with respect to the C=N double bond, and two independent water mol-ecules. In the crystal, the Schiff base and water mol-ecules are linked into a three-dimensional network via N-H⋯O, O-H⋯N, O-H⋯O and C-H⋯O hydrogen bonds. Th...

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2-(1,3-Dioxoisoindolin-2-yl)acetic acid–N′-[(E)-4-meth­oxy­benzyl­idene]pyridine-4-carbohydrazide (2/1)

In the crystal structure of the title compound, 2C(10)H(7)NO(4)·C(14)H(13)N(3)O(2), the two independent acid mol-ecules are connected through strong O-H⋯N and O-H⋯O hydrogen bonds to the central mol-ecule of the anti-tubercular drug N'-[(E)-4-meth-oxy-benzyl-idene]pyridine-4-carbohydrazide. Two such trimolecular units related by an inversion centre inter-act through a pair of N-H⋯O hydrogen bon...

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N′-[(E)-2-Hy­droxy-5-meth­oxy­benzyl­idene]pyridine-4-carbohydrazide monohydrate

The title compound, C14H13N3O3·H2O, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. An intra-molecular O-H⋯N hydrogen bond occurs. In the crystal, the lattice water molecule plays a major role in the supramolecular architecture by interconnecting adjacent molecules into a three-dimensional netwrok by means of O-H⋯O, O-H⋯N and N-H⋯O hydrogen-bondi...

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N′-[(E)-4-Bromo­benzyl­idene]-1-benzofuran-2-carbohydrazide monohydrate

The title compound, C(16)H(11)BrN(2)O(2)·H(2)O, exists in a trans conformation with respect to the N=C bond [1.2815 (14) Å] and the benzofuran ring system forms a dihedral angle of 2.96 (5)° with the benzene ring. In the crystal, the ketone O atom accepts two O-H⋯O and one C-H⋯O hydrogen bond, and the water O atom accepts an N-H⋯O inter-action. Together, these lead to infinite layers lying para...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812017369